![]() As a general rule, in the case of the representative elements, the distinguishing electron will be in an ns or np subshell. In the third period the 3 s subshell is filling for Na and Mg, and therefore Al, Si, P, S, Cl, and Ar. Across the second period Li and Be have distinguishing electrons in the 2 s subshell, and electrons are being added to the 2 p subshell in the atoms from B to Ne. In the first period the distinguishing electrons for H and He are in the 1 s subshell. The first three horizontal rows or periods in the modern periodic table consist entirely of representative elements. Formulas for chlorides of the first dozen elements that show the periodic variation of valence Element This agrees with the valence rules derived from the periodic table, and results in formulas for chlorides of the first dozen elements that show the periodic variation of valence. For representative elements the number of valence electrons is the same as the periodic group number, and the number needed to match the next noble-gas configuration is 8 minus the group number. That is, the valences of the representative elements may be predicted on the basis of the number of valence electrons they have, or from the number of electrons that would have to be added in order to attain the same electron configuration as an atom of a noble gas. Many of the chemical properties of the representative elements can be explained on the basis of Lewis diagrams. Most of the elements whose chemistry and valence we have discussed so far fall into this category. The representative elements are those in which the distinguishing electron enter an s or p subshell. The type of subshell ( s, p, d, f)into which the distinguishing electron is placed is very closely related to the chemical behavior of an element and gives rise to the classification shown by the color-coding on the periodic table seen here. ![]() This last electron is called the distinguishing electron because it distinguishes an atom from the one immediately preceding it in the periodic table. Since it is the outermost (valence) electrons which are primarily involved in chemical interactions between atoms, the last electron added to an atom in the building-up process is of far more interest to a chemist than the first. The commonly used long form of the periodic table is designed to emphasize electron configurations. Therefore, there are various non-equivalent definitions of atomic radius.\) However, this assumes the atom to exhibit a spherical shape, which is only obeyed for atoms in vacuum or free space. The atomic radius of a chemical element is a measure of the distance out to which the electron cloud extends from the nucleus. It must be noted, atoms lack a well-defined outer boundary. The atomic radius of Thallium atom is 145pm (covalent radius). Note that, each element may contain more isotopes, therefore this resulting atomic mass is calculated from naturally-occuring isotopes and their abundance. The atomic mass is carried by the atomic nucleus, which occupies only about 10 -12 of the total volume of the atom or less, but it contains all the positive charge and at least 99.95% of the total mass of the atom. The atomic mass or relative isotopic mass refers to the mass of a single particle, and therefore is tied to a certain specific isotope of an element. Mass numbers of typical isotopes of Thallium are 203, 205. Isotopes are nuclides that have the same atomic number and are therefore the same element, but differ in the number of neutrons. The difference between the neutron number and the atomic number is known as the neutron excess: D = N – Z = A – 2Z.įor stable elements, there is usually a variety of stable isotopes. Neutron number plus atomic number equals atomic mass number: N+Z=A. ![]() The total number of neutrons in the nucleus of an atom is called the neutron number of the atom and is given the symbol N. The total electrical charge of the nucleus is therefore +Ze, where e (elementary charge) equals to 1,602 x 10 -19 coulombs. Total number of protons in the nucleus is called the atomic number of the atom and is given the symbol Z. Thallium is a chemical element with atomic number 81 which means there are 81 protons in its nucleus. Atomic Number – Protons, Electrons and Neutrons in Thallium
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